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Synthesis of unsaturated phosphatidyl inositol‐3,4,5‐trisphosphate

 

作者: Ozaki Shoichiro,   Kong Xiang‐Zheng,   Watanabe Yutaka,   Ogasawara Tomio,  

 

期刊: Chinese Journal of Chemistry  （WILEY Available online 1998）
卷期: Volume 16, issue 1  

页码: 51-57

 

ISSN:1001-604X

 

年代: 1998

 

DOI:10.1002/cjoc.19980160109

 

出版商: Wiley‐VCH Verlag GmbH&Co. KGaA

 

关键词: 1‐(1′, 2′‐Di‐O‐oleoyl‐3′‐sn‐phosphatidyl)‐myo‐inositol‐3,4,5‐tris(hydrogen phosphate);myo‐inositol;unsaturated fatty acid;PI‐3,4,5‐P3

 

数据来源: WILEY

 

摘要:

AbstractPhosphatidylinositol polyphosphate (PIPx) are related with tyrosine kinase activation and cell proliferation and carcinogenesis. PIPxis an important target compound for synthetic organic chemist. PIPxhaving saturated fatty acid components have been reported. Recently we have succeeded in the synthesis of phosphatydylinositol‐3,4,5‐trisphosphate with unsaturated fatty acid component by the reaction of diethyl chlorophosphite with 1,2‐di‐O‐cyclohexylidene‐3,4‐0‐(tetraisopropyldisiloxane 1,3‐diyl)‐6‐O‐(4‐o

 

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