Prediction of Gas Solubilities by a Modified UNIFAC‐Equation
作者:
G. Nocon,
U. Weidlich,
J. Gmehling,
U. Onken,
期刊:
Berichte der Bunsengesellschaft für physikalische Chemie
(WILEY Available online 1983)
卷期:
Volume 87,
issue 1
页码: 17-23
ISSN:0005-9021
年代: 1983
DOI:10.1002/bbpc.19830870107
出版商: Wiley‐VCH Verlag GmbH&Co. KGaA
关键词: Case;Gaslöslichkeit;Phasengleichgewicht;Stoffeigenschaften;Thermodynamik;UNIFAC
数据来源: WILEY
摘要:
AbstractThe design of absorption processes requires the knowledge of gas solubility data. Because experimental data are often not available, an estimation method must be used. Various methods for the prediction of gas solubilities have been published in the literature. It is shown that none of the described methods provides satisfactory prediction results. Therefore a new method – the modified UNIFAC method – is proposed. This modification of the UNIFAC method takes into account free volume effects. The method has been used successfully for the estimation of carbon dioxide, methane, oxygen and ethylene solubilities in aliphatic hydrocarbons and alcohols at 1
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