Analytical Equation of State for Water Compressed to 300 Kbar
作者:
G. A. Gurtman,
J. W. Kirsch,
C. R. Hastings,
期刊:
Journal of Applied Physics
(AIP Available online 1971)
卷期:
Volume 42,
issue 2
页码: 851-857
ISSN:0021-8979
年代: 1971
DOI:10.1063/1.1660103
出版商: AIP
数据来源: AIP
摘要:
An analytical form for the equation of state of water in the region 0.5–300 kbar is presented. The functional form of the equation was first proposed by Born to characterize the melting of crystalline solids, and is applied to water in the thermodynamic vicinity of the Hugoniot. The derived equation is equivalent to the Mie‐Gru¨neisen equation of state if the specific heat at constant volumeCVis taken as a constant. This restriction results in a simple expression for internal energy in terms of temperature and specific volume. This expression contains an undefined function of volume which is shown to be calculable from the available experimental data. The resulting formulation agrees with existing data for condensed states of water to a high degree of accuracy in the region from 0.5 to 300 kbar.
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