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Dynamic mechanical properties of polyurethane networks containing sodium tetraphenylborate, 2. The modulus dependence on temperature, frequency, and salt concentration

 

作者: Andréas Killis,   Jean‐François Le Nest,   Alessandro Gandini,   Hervé Cheradame,  

 

期刊: Die Makromolekulare Chemie  (WILEY Available online 1982)
卷期: Volume 183, issue 4  

页码: 1037-1050

 

ISSN:0025-116X

 

年代: 1982

 

DOI:10.1002/macp.1982.021830426

 

出版商: Hüthig&Wepf Verlag

 

数据来源: WILEY

 

摘要:

AbstractThe viscoelastic behaviour of polyether‐based polyurethane networks containing sodium tetraphenylborate was investigated by means of dynamic mechanical measurements. A quantitative analysis of the storage modulus dependence on temperature, frequency, and salt concentration gives rise to three superposition correlations, viz. frequency‐temperature, frequency‐concentration, and concentration‐temperature. The frequency‐temperature superposition follows a WLF behaviour, while the other two are approximately linear expressions particularly well verified in the zone of the transit

 

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