Dynamic mechanical properties of polyurethane networks containing sodium tetraphenylborate, 2. The modulus dependence on temperature, frequency, and salt concentration
作者:
Andréas Killis,
Jean‐François Le Nest,
Alessandro Gandini,
Hervé Cheradame,
期刊:
Die Makromolekulare Chemie
(WILEY Available online 1982)
卷期:
Volume 183,
issue 4
页码: 1037-1050
ISSN:0025-116X
年代: 1982
DOI:10.1002/macp.1982.021830426
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractThe viscoelastic behaviour of polyether‐based polyurethane networks containing sodium tetraphenylborate was investigated by means of dynamic mechanical measurements. A quantitative analysis of the storage modulus dependence on temperature, frequency, and salt concentration gives rise to three superposition correlations, viz. frequency‐temperature, frequency‐concentration, and concentration‐temperature. The frequency‐temperature superposition follows a WLF behaviour, while the other two are approximately linear expressions particularly well verified in the zone of the transit
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