Trialkylsulfonium- and Trialkylselenoniumhydroxides for the Pyrolytic Alkylation of Acidic Compounds
作者:
W. Butte,
J. Eilers,
M. Kirsch,
期刊:
Analytical Letters
(Taylor Available online 1982)
卷期:
Volume 15,
issue 10
页码: 841-850
ISSN:0003-2719
年代: 1982
DOI:10.1080/00032718208069519
出版商: Taylor & Francis Group
关键词: wrolytic alkylation;flash heat alkylation;on column alkylation;acidic compounds;trialkylsulfonium-hydroxide;trialkylselenoniumhydroxide
数据来源: Taylor
摘要:
Trialkylsulfonium- and trialkylselenoniumhydroxides are pyrolytic alkylation reagents that derivatize acidic compounds quantitatively inside the injector of the gas chromatograph. Trimethyl-sulfoniumhydroxide and Triethylsulfoniumhydroxide, the analogues of selenium respectively are stable in cool methanol solution for at least 6 months. The reagents are easy to handle and the byproducts formed are very volatile. Therefore the application of ternary sulfonium- and selenoniumhydroxides is equivalent or even superior to the use of the well known quartary ammoniumhydroxides.
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