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Incorporation of oxygen and chlorine atoms into low‐temperature (850 °C) silicon epitaxial films by chemical vapor deposition

 

作者: Akihiro Miyauchi,   Kazuhiro Ueda,   Yousuke Inoue,   Takaya Suzuki,   Yoshinori Imai,  

 

期刊: Applied Physics Letters  (AIP Available online 1995)
卷期: Volume 66, issue 21  

页码: 2867-2869

 

ISSN:0003-6951

 

年代: 1995

 

DOI:10.1063/1.113456

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A correlation between the partial pressure of dichlorosilane gas (SiH2Cl2) and the incorporation of oxygen (O) and chlorine (Cl) atoms into the low‐temperature (850 °C) epitaxial films was found. The profiles of O and Cl concentrations in the epitaxial films were measured by secondary ion mass spectroscopy. Incorporation of O and Cl atoms into the growth films during the epitaxial growth was suppressed by increasing the partial pressure of SiH2Cl2. The growth rate linearly increased with the partial pressure of SiH2Cl2and eventually saturated. Incorporation of O atoms was inhibited and fine removal of Cl atoms was achieved when the growth rates saturated. The epitaxial films with high O and Cl concentrations had a microroughened surface (root mean square of microroughness ≳0.4 nm). The microroughness was also improved by increasing the partial pressure of SiH2Cl2. The coverage of kinks and/or hollow bridge sites by hydrogen (H) and Cl atoms seems to restrict the reaction of O and water (H2O) with the growth front surface. ©1995 American Institute of Physics. 

 

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