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Modified Fokker-Planck equations

 

作者: GlennT. Evans,  

 

期刊: Molecular Physics  (Taylor Available online 1978)
卷期: Volume 36, issue 1  

页码: 65-78

 

ISSN:0026-8976

 

年代: 1978

 

DOI:10.1080/00268977800101401

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A rotational FP-like equation is derived for the motion of a tagged diatomic molecule in a bath of diatomics possessing rotational and translational degrees of freedom. The torque correlation operator in the FP-like equation has contributions from (1) rotation-translation coupling; (2) collisions which change the orientation of the molecule as well as its momentum; and (3) non-linear momentum relaxation. An approximate improved FP collision operator is suggested and is employed in the calculation of the orientational distribution function and correlation time,τl, for a high density fluid in the strong collision regime. A translational FP equation for non-spherical molecules is also obtained by analogy with the rotational case.

 

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