Ab initiostudies on the pyrolysis mechanism of 2‐haloacetic acids in the gas phase
作者:
Li‐Tao Chen,
Guang‐Ju Chen,
Xiao‐Yuan Fu,
期刊:
Chinese Journal of Chemistry
(WILEY Available online 1995)
卷期:
Volume 13,
issue 1
页码: 10-18
ISSN:1001-604X
年代: 1995
DOI:10.1002/cjoc.19950130103
出版商: Wiley‐VCH Verlag GmbH&Co. KGaA
关键词: 2‐Haloacetic acid;pyrolysis;reaction mechanism;transition state.
数据来源: WILEY
摘要:
AbstractThe dehydrohalogenation mechanism of 2‐haloacetic acids (XCH2CO2H, X=F, Cl and Br) has been studied theoretically by HF/3–21G and AM1 methods. The results indicate that these reactions are most probably proceeded in terms of a polar five‐membered cyclic transition state in the gas phase. Their microscopic processes are beleived to be a stepwise reaction and the rate‐determining step is the first one. By comparing the energy barriers of different 2‐haloacetic acids, it can be realized that 2‐fluoroacetic acid is easier to react than 2‐chloroacetic and 2‐br
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