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Direct evidence for Vo¨gel–Fulcher freezing in relaxor ferroelectrics

 

作者: A. E. Glazounov,   A. K. Tagantsev,  

 

期刊: Applied Physics Letters  (AIP Available online 1998)
卷期: Volume 73, issue 6  

页码: 856-858

 

ISSN:0003-6951

 

年代: 1998

 

DOI:10.1063/1.122024

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Direct evidence for freezing in two relaxor ferroelectrics,PbMg1/3Nb2/3O3andPbSc1/2Ta1/2O3,at a certain temperatureTf≠0 Kwas obtained from the temperature dependence of the maximum relaxation time,&tgr;max.It was shown that&tgr;max(T)follows the Vo¨gel–Fulcher (VF) law, and tends toward infinity as temperature approachesTf.The freezing temperatureTfderived from&tgr;max(T)coincides with the value ofTfobtained from the fit of frequency, &ohgr;, dependence of the temperature,Tmax,of the dielectric permittivity maximum to the same VF law. Thus, this result solves the controversy that the VF law for&ohgr;(Tmax)may not correspond to the freezing of the spectrum. ©1998 American Institute of Physics.

 

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