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Concentration Effects on Averaged Transport Coefficients for Polymer Solutions in Narrow Pores

 

作者: Douglas B. Adolf,   Matthew Tirrell,  

 

期刊: Journal of Rheology  (AIP Available online 1986)
卷期: Volume 30, issue 3  

页码: 539-554

 

ISSN:0148-6055

 

年代: 1986

 

DOI:10.1122/1.549859

 

出版商: The Society of Rheology

 

数据来源: AIP

 

摘要:

A phenomenological model describing the effects of non‐infinitely dilute polymer concentrations on average transport coefficients for polymer solutions in narrow pores is developed using gradient theory applied to transport processes. Average viscosities and diffusion coefficients are calculated and fit to experimental rheological data using the one adjustable parameter of the model. The concentration dependence of this parameter is examined and found to be in agreement with intuition and existing theories.

 

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