Sorption Equilibrium in Relation to the Spatial Distribution of Molecules – Application to Desorption of Potato
作者:
Lars Malmquist,
Ove Sodentrom,
期刊:
Drying Technology
(Taylor Available online 1997)
卷期:
Volume 15,
issue 3-4
页码: 1159-1172
ISSN:0737-3937
年代: 1997
DOI:10.1080/07373939708917284
出版商: Taylor & Francis Group
关键词: sorption;equilibrium;heat of reaction;degrees of freedom;swelling
数据来源: Taylor
摘要:
An analysis of desarption isotherms for potato shows the following probable qualities in the water-potato sysarn. in the natural staa the walcr is bound rather strongly due to loss of rotational degrees of freedom in the sorbed molecules, which is caused by small molecular voids in the cellulose structure. This strucmre therefore is formcd as a uniformly cross bound state of the OH-groups. This slate prevails up to a cenin temperature, above which a reaction sas in. whcre OH bonds are successively braken, giving passibility for a panial rotation of sorbed molecules. in the range of lower moisture conlcnt the cellulose strucmre is changed into n crystalline slate a in wood, although the dcgrcc of crystallinity is lower, which is thc
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