Successive Magnetic Phase Transitions of CucCo1-cCl2-FeCl3Graphite bi-intercalation Compounds
作者:
ItsukoS. Suzuki,
Masatsugu Suzuki,
Hirohiko Sato,
Toshiaki Enoki,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 2000)
卷期:
Volume 340,
issue 1
页码: 107-112
ISSN:1058-725X
年代: 2000
DOI:10.1080/10587250008025451
出版商: Taylor & Francis Group
关键词: helical spin order;spin glass;reentrant spin glass;random field effect;magnetic phase transition;SQUID AC susceptibility
数据来源: Taylor
摘要:
CucCo1-cCl2-FeCl3graphite bi-intercalation compounds (GBIC's) have a c-axis stacking sequence of -G-I1-G-I2-G-I1-G-I2-G- (G = graphite layer, I1= CucCo1-cCl2layer, and I2= FeCl3layer). These compounds undergo magnetic phase transitions at Th, Tcu, Tcl, TSG, and TRSG(Th>Tcl>TRSG=TSG). depending on the Cu concentration. The phase transition at This related to a helical spin order. The phase transitions at Tcuand Tclare associated with a spin order of CucCo1-cCl2layers. The re-entrant spin glass phase below TRSGfor c≤0.4 and the spin glass phase below TSGfor c≥0.5 are due to the spin frustration effect occurring in FeCl3layers. The nature of these phases has been studied using SQUID DC magnetization and SQUID AC magnetic susceptibility.
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