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NMR Study of the Hydrogen Bonding of Sterically Hindered Phenols with Alicyclic Ethers and Pyridine

 

作者: T.S. Pang,   Soon Ng,  

 

期刊: Spectroscopy Letters  (Taylor Available online 1974)
卷期: Volume 7, issue 8  

页码: 377-380

 

ISSN:0038-7010

 

年代: 1974

 

DOI:10.1080/00387017408067261

 

出版商: Taylor & Francis Group

 

关键词: hydrogen-bond chemical shift;enthalpy change;hindered phenols;alicyclic ethers;pyridine

 

数据来源: Taylor

 

摘要:

In a preliminary report1it was shown that the hydrogen-bond chemical shift, δAB, correlates with the change in enthalpy, δH, in the interaction of chloroform with a series of closely related oxygen and nitrogen bases. In this communication, we report the hydrogen bonding parameters for the interaction in cyclohexane medium between 2,4,6-tri-t-butylphenol and tetrahydrofuran, tetrahydropyran and pyridine, and between 2,6-di-1-adamantyl-4-t-butylphenol and pyridine. There is correlation between the δABand δAEfor the same proton donor (2,4,6-tri-t-butylphenol) and the closely related alicyclic bases, and for the same base (pyridine) and the two closely related sterically hindered phenols. The temperature dependence of the δABin these systems is also reported.

 

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