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Rate constants for the gas phase reactions of the OH radical with CF3CF2CHCl2(HCFC‐225ca) and CF2ClCF2CHClF (HCFC‐225cb)

 

作者: Zhengyu Zhang,   Renzhang Liu,   Robert E. Huie,   Michael J. Kurylo,  

 

期刊: Geophysical Research Letters  (WILEY Available online 1991)
卷期: Volume 18, issue 1  

页码: 5-7

 

ISSN:0094-8276

 

年代: 1991

 

DOI:10.1029/90GL02647

 

数据来源: WILEY

 

摘要:

Rate constants have been measured for the gas phase reactions of the hydroxyl radical (OH) with the hydrochlorofluorocarbons CF3CF2CHCl2(HCFC‐225ca) over the temperature range 270 to 400 K and CF2ClCF2CHClF (HCFC‐225cb) over the temperature range 298 to 400 K. The Arrhenius expressions k(225ca) = (1.92 ± 0.52) × 10−12exp(−1290 ± 90/T) cm3molecule−1s−1and k(225cb) = (6.75 ± 3.70) × 10−13exp(−1300 ± 180/T) cm3molecule−1s−1were deri

 

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