Rate constants for the gas phase reactions of the OH radical with CF3CF2CHCl2(HCFC‐225ca) and CF2ClCF2CHClF (HCFC‐225cb)
作者:
Zhengyu Zhang,
Renzhang Liu,
Robert E. Huie,
Michael J. Kurylo,
期刊:
Geophysical Research Letters
(WILEY Available online 1991)
卷期:
Volume 18,
issue 1
页码: 5-7
ISSN:0094-8276
年代: 1991
DOI:10.1029/90GL02647
数据来源: WILEY
摘要:
Rate constants have been measured for the gas phase reactions of the hydroxyl radical (OH) with the hydrochlorofluorocarbons CF3CF2CHCl2(HCFC‐225ca) over the temperature range 270 to 400 K and CF2ClCF2CHClF (HCFC‐225cb) over the temperature range 298 to 400 K. The Arrhenius expressions k(225ca) = (1.92 ± 0.52) × 10−12exp(−1290 ± 90/T) cm3molecule−1s−1and k(225cb) = (6.75 ± 3.70) × 10−13exp(−1300 ± 180/T) cm3molecule−1s−1were deri
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