Synthesis, polymerization and cation conductive properties of (ω‐carboxy)‐oligo(oxyethylene) methacrylate
作者:
Shinji Takeoka,
Yoshinari Maeda,
Eishun Tsuchida,
Hiroyuki Ohno,
期刊:
Polymers for Advanced Technologies
(WILEY Available online 1990)
卷期:
Volume 1,
issue 3‐4
页码: 201-205
ISSN:1042-7147
年代: 1990
DOI:10.1002/pat.1990.220010302
出版商: John Wiley&Sons, Ltd.
关键词: Solid polymer electrolyte;Polyelectrolyte;Complex impedance plot;Single ionic conductivity;Glass transition temperature
数据来源: WILEY
摘要:
AbstractAlkali‐metal salts of (ω‐carboxy)oligo(oxyethylene) methacrylate (CME12M, M = Li or Cs) have been synthesized and polymerized to prepare solid polymer electrolytes. These types of solid polymer electgrolytes provide a homogeneous phase, since these polymers have a flexible main chain, an oligo(oxyethylene) side chain for ion conduction, and a carrier ion source in one repeating unit. The AC conductivity of P(CME12Li) homopolymer is 8.9 × 10−9S cm−1at 30°C, while that of P(CME12Cs) is 3.3 × 10−6S cm−1at 30°C, which is the highest value among single ion conductors, have been reported as polyelectrolyte “homopolymer” without any additives. High ionic conduction of P(CME12Cs) is due to low glass transition temperature (Tg= −54°C) and weaker ion–ion and ion–dipole interac
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