Selenite adsorption by a variety of oxides consisting of iron (Fe), aluminum (Al), titanium (Ti), manganes (Mn), and silicon (Si), and by two humic acids were investigated in order to grasp selenite behavior and fixation mechanisms in soil. It was found that selenite was apparently adsorbed even by the Mn oxides on which surface negative charge was dominant in normal pH range (pH <4). No selenite adsorption was observed in the silicon dioxide (SiO2) and the two humic acids. A sequential extraction of adsorbed selenite with competitive anions showed the differences of binding force or stability of adsorbed selenite among the minerals. While the goethite fixed selenite strongly, selenite adsorbed on the Mn oxide was easily released to the liquid phase with other anions, such as phosphate. Each mineral had its inherent characteristic in ligand exchange reactions accompanied with selenite sorption. Selenite sorption by the Mn and the Ti oxides resulted in large increase of surface negative charge, while only a little increase in the Fe and Al oxides. Proton consumption with selenite sorption was extremely smaller for the Mn oxide than for the others.