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Oxygen Fugacity Control in Nonflowing Atmospheres: I, Experimental Observations in CO/CO2and O2/N2Mixtures

 

作者: Fernando M. B. Marques,   Gerald P. Wirtz,  

 

期刊: Journal of the American Ceramic Society  (WILEY Available online 1992)
卷期: Volume 75, issue 2  

页码: 369-374

 

ISSN:0002-7820

 

年代: 1992

 

DOI:10.1111/j.1151-2916.1992.tb08189.x

 

出版商: Blackwell Publishing Ltd

 

关键词: oxygen;sensors;zirconia;electrolytes;pumps

 

数据来源: WILEY

 

摘要:

The performance of a stabilized zirconia sensor and electrochemical oxygen pump combination in the isothermal control of oxygen fugacity in a nonflowing atmosphere was studied in a closed furnace system in the temperature range of 800° to 1100°C. Under certain conditions, large differences in oxygen pressure were found between sensors at the same constant temperature in close proximity to each other. This result reflected the existence of a stable steplike oxygen fugacity “front” in the furnace, separating regions which differed by several orders of magnitude in oxygen fugacity. This oxygen pressure profile in the furnace resulted from the steady‐state transport of oxygen from oxygen leakage sources to the pump. The existence, magnitude, and position of the oxygen fugacity front were found to depend on the gas‐phase composition, the relative locations of the leakage sources and the pump, the oxygen fugacity of the reference electrode, and the magnitude of the oxygen flux in the

 

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