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Far-infrared absorption in gaseous CH4and CF4

 

作者: C.G. Joslin,   C.G. Gray,   S. Singh,  

 

期刊: Molecular Physics  (Taylor Available online 1985)
卷期: Volume 54, issue 6  

页码: 1469-1489

 

ISSN:0026-8976

 

年代: 1985

 

DOI:10.1080/00268978500101111

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

We present a simple theory of the gas-phase far-infrared collision-induced absorption spectra of two molecules with tetrahedral symmetry, methane (CH4) and tetrafluoromethane (CF4). We assume that in these molecules CIA arises through octopolar and hexadecapolar induction. By neglecting the small anisotropies in the intermolecular CH4-CH4and CF4-CF4potentials, we can express the spectral profiles as convolutions of single-molecule free rotation spectra with intermolecular translational components. Information theory is used to estimate the ‘least biased’ form for the latter, based on our knowledge of their spectral moments (the calculation of the zeroth through sixth moments is described in an appendix). In this way we avoid the need to make questionable assumptions about the system dynamics. The computed lineshapes are in excellent agreement with the available experimental data.

 

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