Elastic constants of nematic solutions of rod-like and semi-flexible polymers
作者:
Theo Odijk,
期刊:
Liquid Crystals
(Taylor Available online 1986)
卷期:
Volume 1,
issue 6
页码: 553-559
ISSN:0267-8292
年代: 1986
DOI:10.1080/02678298608086279
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Analytical expressions for the elastic constants of nematic polymer solutions are derived when the macromolecules are monodisperse rod-like, bidisperse rodlike or semi-flexible. These expressions are derived in the gaussian approximation so that they constitute exact leading terms of a general asymptotic expansion for high degree of nematic ordering although the results are justifiable only within the range of validity of the second virial approximation. The limiting forms are in complete agreement with recent numerical work for monodisperse rods.
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