KINETIC EFFECTS OF SURFACTANT / POLYMER MIXTURES UPON ACIDIC HYDROLYSIS OF HYDROXAMIC ACIDS
作者:
KallolK. Ghosh,
Alka Pandey,
期刊:
Journal of Dispersion Science and Technology
(Taylor Available online 1999)
卷期:
Volume 20,
issue 6
页码: 1635-1646
ISSN:0193-2691
年代: 1999
DOI:10.1080/01932699908943878
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The influence of surfactant / polymer (polyethylene glycol, PEG, mol. wt. = 400) mixtures upon the acidic hydrolysis of two N-substituted hydroxamic acids, i.e., R(CO). N(OH)R' : R = C6H5, R' = C6H5;4-CH3C6H4has been studied using cationic (CTAB, TTAB and CPC) and nonionic (TX-100 and Brij-35) surfactants. An inhibitory effect was observed. The results have been explained by Porinoy - Menger model. The critical aggregation concentration and polymer saturation point of the corresponding systems have also been measured with the conductivity and surface tension methods.
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