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Electrochemical oxidation of 1,3-diketones in the presence of hydrohalic acid salts

 

作者: M.N.Élinson,   T.L.Lizunova,   G.I.Nikishin,  

 

期刊: Bulletin of the Russian Academy of Sciences, Division of chemical science  （Springer Available online 2004）
卷期: Volume 41, issue 1  

页码: 123-126

 

ISSN:1063-5211

 

年代: 2004

 

DOI:10.1007/BF00863926

 

出版商: Springer_US-Boston

 

数据来源: Springer

 

摘要:

In the presence of a mediator (sodium iodide) acetylacetone dimerizes with the formation of 3,4-diacetylhexane-2,5-dione, with a yield up to 90%. Salts of 2-halosubstituted 1,3-diketones form more highly enolized cyclic 1,3-diketones — 1,3-cyclohexanedione and dimedone under analogous conditions, with a yield up to 90

 

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