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SAXS studies of blends of high- and low-density polyethylene

 

作者: C. Reckinger,   F.C. Larbi,   J. Rault,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1984)
卷期: Volume 23, issue 4-6  

页码: 511-526

 

ISSN:0022-2348

 

年代: 1984

 

DOI:10.1080/00222348408219474

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

It is shown that in blends of PE having different melting temperatures the morphology depends drastically on the cooling rate. In these heterogeneous PE, the correlation relationship L = r between the long period L of the solid state and the dimension of the coils r in the liquid state is observed only in rapidly quenched materials. In slowcooled materials the SAXS spectra are interpreted in terms of segregation of two types of PE, on a scale of the order of the dimension of the coils, the arrangement of the crystalline lamellae being paracrystalline and statistical.

 

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