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An analysis of the effects of atmospheric sulphate and ammonium on soil solution chemistry using median polishing

 

作者: P. J. A Howard,  

 

期刊: Journal of Applied Statistics  (Taylor Available online 1993)
卷期: Volume 20, issue 1  

页码: 119-126

 

ISSN:0266-4763

 

年代: 1993

 

DOI:10.1080/02664769300000009

 

出版商: Carfax Publishing Company

 

数据来源: Taylor

 

摘要:

Soils from locations near Amsterdam, Dublin, Exeter (SW England), Göttingen, Paris and in the Grizedale Forest (NW England) were placed in lysimeters in a Norway spruce (Picea abies) stand in the Grizedale Forest and the soil solutions, rainfall and throughfall were monitored for 54 weeks. Two-way data tables for SO4, NH4, NO3, Al, Mg, Ca and pH were analysed by median polishing, in which each observed data value is decomposed into a typical value plus a row effect plus a column effect plus a residual. The row effects suggested that SO4 was the main acidifying influence in the Göttingen soil, but in the other soils SO4 had less effect than did NO3. The column effects showed little variation over the 54 weeks. Low values for NO3 in March-May and September were associated with periods of low or zero rainfall. The residuals contained from 27% (Al) to 59% (NO3) of the variation. Some were interpretable and contained useful information. Where the residuals are considered to represent uninterpretable random variation (‘noise’) they can be subtracted from the original data to give corrected data for other types of analysis. In median polishing, changing a few values in the input data, even drastically, will result in unusual residuals only in the cells with altered values. Hence, it is a useful technique for screening two-way data tables obtained from field experiments.

 

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