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Theory of Phase Transitions in the Assembly of Biaxial Molecules Interacting via Dispersion Forces

 

作者: Masahito Hosino,   Huzio Nakano,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 2000)
卷期: Volume 348, issue 1  

页码: 207-225

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008024807

 

出版商: Taylor & Francis Group

 

关键词: biaxial molecules;induced dipole-dipole interaction

 

数据来源: Taylor

 

摘要:

The ordering in the assembly of biaxial molecules which interact pairwise via the dispersion force is investigated statistical-mechanically, where four kinds of liquid crystalline phase and phase transitions between some pairs of those phases are discussed in comparison with the existing theoretical results from the model of uniaxial molecules. There appear one uniaxial nematic phase, two kinds of biaxial nematic phase and one discotic phase. The phase diagram of temperature versus interaction strength are obtained, where the four phases mentioned above appear in different regions depending on the molecular shape. Some advantages of the present method in investigating the orientational ordering in biaxial liquid crystals, including the discotic phases, are discussed.

 

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