Square wave electrolysis. I. The cyclic potential‐step method
作者:
W. M. Smit,
M. D. Wijnen,
期刊:
Recueil des Travaux Chimiques des Pays‐Bas
(WILEY Available online 1960)
卷期:
Volume 79,
issue 1
页码: 5-21
ISSN:0165-0513
年代: 1960
DOI:10.1002/recl.19600790102
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
AbstractDrawbacks of the well‐known potential‐step method are briefly mentioned. A new method called thecyclicpotential‐step method is introduced, the essential of which is that a square wave voltage is applied to a polarisable electrode. It is shown mathematically that the current response approaches rapidly to a constant pattern. The derivations presented are free from restrictions concerning the reversibility of the system and the magnitude of the amplitude of the square wave.It is shown that the cyclic potential‐step method offers easy means for the determination of the transfer‐coefficient (α) and the standard exchange current den
点击下载:
PDF
(671KB)
返 回