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Comparison of the Intercalation into Graphite of Phosphorus-Potassium and Mercury-Potassium Binaries

 

作者: Frederique Goutfer-wurmser,   Claire Herold,   Jean-François Mareche,   Philippe Lagrange,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 2000）
卷期: Volume 340, issue 1  

页码: 229-234

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008025471

 

出版商: Taylor & Francis Group

 

关键词: graphite;mercury;phosphorus;potassium;ternary GICs;electrical resistivity

 

数据来源: Taylor

 

摘要:

Potassium-phosphorus binaries are able to intercalate into graphite as potassium-oxygen or potassium-sulphur binaries, so that phosphorus behave as a classical electronegative element. But, it is able, on the other hand, to behave as a metal such as mercury, so that potassium-phosphorus and potassium-mercury binaries intercalate into graphite by very close synthesis routes. Phosphorus appears thus as a linking element between strongly and fairly electronegative species.

 

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