Precursor to paramagnetic centers induced in gamma‐irradiated doped silica glasses
作者:
Koichi Awazu,
Hiroshi Kawazoe,
Koushi Harada,
Kazuhiro Kido,
Satoru Inoue,
期刊:
Journal of Applied Physics
(AIP Available online 1993)
卷期:
Volume 73,
issue 4
页码: 1644-1649
ISSN:0021-8979
年代: 1993
DOI:10.1063/1.353198
出版商: AIP
数据来源: AIP
摘要:
We prepared silica glasses having various concentrations of chlorine, fluorine, hydrogen (SiO2−x), and oxygen (SiO2+x) to examine the precursors of paramagnetic centers induced by &ggr; rays. In the case of glasses sintered under chlorine and hydrogen ambients, the concentration of theE’center induced by &ggr;‐ray irradiation scaled with the partial pressure of chlorine and hydrogen. In contrast, theE’center was suppressed in glasses doped with fluorine. Stress in the glasses was also found to enhance formation of theE’center. Planar ring structures in the glass are influenced by stress and are proposed as precursors to theE’center.
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