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Stereoselective Synthiesis of Both Enantiomers of Disparlure from D-Glucose

 

作者: Osman Achmatowicz,   Andrzej Sadownik,  

 

期刊: Journal of Carbohydrate Chemistry  （Taylor Available online 1985）
卷期: Volume 4, issue 3  

页码: 435-440

 

ISSN:0732-8303

 

年代: 1985

 

DOI:10.1080/07328308508070193

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

D-Glucose was transformed stereoselectively into (7R,8S)8-benzyloxy-7-hydroxy-2-methyl-9-octadecene from which both enantiomers of disparlure, (7R,8S)-(+)-and (7S,8R)-(-)-7,8-epoxy-2-methyloctadecane, sex pheromone of the gypsy moth, were obtained in four and three steps, respectively.

 

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