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Internal viscosity in the dynamics of polymer molecules

 

作者: D. A. Macinnes,  

 

期刊: Journal of Polymer Science: Polymer Physics Edition  (WILEY Available online 1977)
卷期: Volume 15, issue 3  

页码: 465-476

 

ISSN:0098-1273

 

年代: 1977

 

DOI:10.1002/pol.1977.180150306

 

出版商: John Wiley&Sons, Inc.

 

数据来源: WILEY

 

摘要:

AbstractWe consider the internal viscosity (IV) of polymer molecules in solution, and investigate how the IV might depend on solvent viscosity η0. From the Kirkwood model of a polymer, we derive in a nonrigorous manner two equations containing an IV, one equation valid for low η0and the other for high η0, and we show that in these respective cases the coefficient of the IV is independent of η0and linearly dependent on

 

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