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Solution of the mean spherical model for dipolar mixtures

 

作者: Dennis Isbister,   RichardJ. Bearman,  

 

期刊: Molecular Physics  (Taylor Available online 1974)
卷期: Volume 28, issue 5  

页码: 1297-1304

 

ISSN:0026-8976

 

年代: 1974

 

DOI:10.1080/00268977400102611

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The mean spherical model is solved analytically for mixtures of dipolar fluids. The components are identified by different but additive molecular radii and different magnitudes of the dipole moment. The direct and indirect correlation functions are found to be functionally dependent on the corresponding hard-sphere functions calculated at certain adjusted densities. Equations for the parameters concerned in calculating such densities are given. The reduction to the equal radii case follows immediately from this analysis.

 

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