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Note Aminolytic Degradation of Polyesters

 

作者: V.A. Popoola,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1989)
卷期: Volume 26, issue 7  

页码: 999-1005

 

ISSN:0022-233X

 

年代: 1989

 

DOI:10.1080/00222338908052026

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Esters are usually prepared by the acid-catalyzed reaction of alcohols and phenols with acids or acid derivatives, such as acid chlorides and anhydrides. In the presence of the reaction products, the esterification step is followed by the similar acid-catalyzed homogeneous hydrolysis of the polymer. Both the formation of the polymer and the hydrolysis reaction that follows are accompanied by considerable degradation of the polymer chain leading to deterioration of the polymer end-use properties.

 

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