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Statistical-Mechanical Model for Calculating Equilibrium Properties of Systems Composed of Interacting Ellipsoidal Molecules at a Solid Surface

 

作者: A.V. Zakharov,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 1995)
卷期: Volume 264, issue 1  

页码: 191-200

 

ISSN:1058-725X

 

年代: 1995

 

DOI:10.1080/10587259508037312

 

出版商: Taylor & Francis Group

 

关键词: Mean force potentials;system of the nonlinear integral equations

 

数据来源: Taylor

 

摘要:

We have proposed a statistical-mechanical theory of a nematic liquid crystal composed of ellipsoidal molecules interacting through angle-dependent nonseparable potentials in contact with a solid interacting surface. The theory takes into account pair intermolecular correlations. Within the framework of the theory the concept of an average force potential is used to develop a truncation procedure for arbitrary equation of the chain. The closed system of integral equations for average force potential is similar to that used by Brook-Levinson and Zakharov for uniform nematic phase. These equations are solved numerically and results are given for the cubic closed packing ellipsoidal molecules interacting through Berne–Pechukas potentials. Although the calculations have been made for the nematic liquid crystal, the general approach can be applied to any liquid crystalline phase.

 

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