Statistical-Mechanical Model for Calculating Equilibrium Properties of Systems Composed of Interacting Ellipsoidal Molecules at a Solid Surface
作者:
A.V. Zakharov,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1995)
卷期:
Volume 264,
issue 1
页码: 191-200
ISSN:1058-725X
年代: 1995
DOI:10.1080/10587259508037312
出版商: Taylor & Francis Group
关键词: Mean force potentials;system of the nonlinear integral equations
数据来源: Taylor
摘要:
We have proposed a statistical-mechanical theory of a nematic liquid crystal composed of ellipsoidal molecules interacting through angle-dependent nonseparable potentials in contact with a solid interacting surface. The theory takes into account pair intermolecular correlations. Within the framework of the theory the concept of an average force potential is used to develop a truncation procedure for arbitrary equation of the chain. The closed system of integral equations for average force potential is similar to that used by Brook-Levinson and Zakharov for uniform nematic phase. These equations are solved numerically and results are given for the cubic closed packing ellipsoidal molecules interacting through Berne–Pechukas potentials. Although the calculations have been made for the nematic liquid crystal, the general approach can be applied to any liquid crystalline phase.
点击下载:
PDF (483KB)
返 回