Nanocrystalline copper doped zinc oxide gas sensors
作者:
AlanV. Chadwick,
Annette Harsch,
NigelV. Russell,
KimF. Tse,
AdamR. Whitham,
Alan Wilson,
期刊:
Radiation Effects and Defects in Solids
(Taylor Available online 1995)
卷期:
Volume 137,
issue 1-4
页码: 51-55
ISSN:1042-0150
年代: 1995
DOI:10.1080/10420159508222692
出版商: Taylor & Francis Group
关键词: Nanocrystals;doped zinc oxide;EXAFS;gas sensing
数据来源: Taylor
摘要:
Samples of nanocrystalline Cu doped ZnO have been prepared and characterised by several techniques including chemical analysis, X-ray powder diffraction and X-Ray absorption spectra (EXAFS). The particle sizes are typically less than 100 Å on the largest diameter. The diffraction results show that lightly doped samples, less than 10 mole per cent Cu, are single phase with the ZnO crystal structure. The EXAFS results indicate that although the Zn2+ions occupy normal cation sites the Cu2+ions are in highly disordered sites, suggesting that there is possible surface aggregation. Gas sensing experiments show a good response to low ppm concentrations of toluene vapour.
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