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Wide‐band solids, rapid recovery, multinuclear transceiver/digitizer for a high‐resolution NMR spectrometer

 

作者: T. C. Claiborne,   J. T. Cheng,   A. R. Garber,   P. D. Ellis,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1987)
卷期: Volume 58, issue 5  

页码: 742-754

 

ISSN:0034-6748

 

年代: 1987

 

DOI:10.1063/1.1139625

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A transceiver which is capable of observation of spectral widths of 1.6 MHz has been constructed as an accessory to a Bruker WH‐400 NMR spectrometer. This device permits observation of the NMR resonances of solid‐state quadrupolar nuclei, which may contain frequency components more than 1 MHz away from their fundamental precession frequencies. The transceiver contains its own frequency generation section, which employs the host spectrometer’s master phase reference and synthesizer. The NMR signal undergoes image rejection mixing to an intermediate frequency above the observation band, and quadrature phase detection before final amplification with video speed operational amplifiers in the receiver section. Dual 8‐bit, video speed digitizers feed the converted data to dual 16 kword deep buffers that can accept data at a rate of 4 Msamples/s. A slower data output rate is governed by the Bruker Aspect host computer. The noise figure of the device is 1.8 dB, with a sensitivity of at least −71 dBm and a recovery time of approximately 1 &mgr;s for linear amplification to resume after an excitation pulse.

 

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