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Tungsten etching in pulsed SF6plasmas

 

作者: R. Petri,   B. Kennedy,   D. Henry,   N. Sadeghi,   J.‐P. Booth,  

 

期刊: Journal of Vacuum Science&Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena  (AIP Available online 1994)
卷期: Volume 12, issue 5  

页码: 2970-2975

 

ISSN:1071-1023

 

年代: 1994

 

DOI:10.1116/1.587544

 

出版商: American Vacuum Society

 

关键词: TUNGSTEN;ETCHING;PLASMA SOURCES;SULFUR FLUORIDES;ADSORPTION;TEMPERATURE EFFECTS;PRESSURE EFFECTS;PULSES

 

数据来源: AIP

 

摘要:

Tungsten etching in pulsed plasmas has been investigated in a helicon plasma source reactor. The time dependence of the fluorine atom concentration has been measured using the time‐resolved actinometry technique and related to the etch rate. According to our observations, it appears that fluorine adsorption on the tungsten substrate surface continues in the post‐discharge period until the surface saturates. Moreover, it appears that two etching regimes exist. For short discharge off periods, the etching is limited by the fluorine adsorption ability of the surface, whereas for long periods, the etching is limited by the desorption rate of the etch products. Experiments were performed at different substrate temperatures and plasma gas pressures. An empirical model has been developed, in good agreement with the experimental data.

 

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