Preparation of an aromatic hydroxylamine and some cyclic hydroxamic acids, and their reaction with hydrochloric acid
作者:
R. T. Coutts,
N. J. Pound,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1970)
卷期:
Volume 48,
issue 12
页码: 1859-1864
ISSN:0008-4042
年代: 1970
DOI:10.1139/v70-306
出版商: NRC Research Press
数据来源: NRC
摘要:
The reduction of 2,3-dimethyl-4-(o-nitrophenylthio)-1-phenyl-3-pyrazolin-5-one by sodium borohydride and palladium–charcoal gave the corresponding hydroxylamine. The action of hydrochloric acid on this hydroxylamine gave thep-chloroamine. In a similar manner, treatment of some 2H-1,4-benzothiazine and -benzoxazine hydroxamic acids with hydrochloric acid resulted in the formation of 7-chloro-2H-1,4-benzothiazine and -benzoxazine lactams.
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