Volumetric and Ultrasonic Behaviour of 1,2-Dibromoethane With a Ketone
作者:
P. Venkateswarlu,
N.V. Choudary,
A. Krishnaiah,
G.K. Raman,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1986)
卷期:
Volume 15,
issue 3
页码: 203-215
ISSN:0031-9104
年代: 1986
DOI:10.1080/00319108608078481
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
New experimental data for excess volume and sound velocity in binary liquid mixtures of 1,2-dibromoethane with methyl ethyl ketone, diethyl ketone, methyl propyl ketone, methyl isobutyl ketone, cyclopentanone and cyclohexanone at 303.15 K have been reported. The results have been analysed in terms of free length theory (FLT) and collision factor theory (CFT). Molar sound velocity(R), molar compressibility(W)and van der Waals constant(b)have also been computed. The sound velocity data were also used along with densities to compute isentropic compressibilities(ks). The excess volumes(VE)and the deviation in isentropic compressibilities (Δks) are used to understand the interactions between unlike molecules.
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