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55Mn Nuclear Magnetic Resonance in MnO

 

作者: E. D. Jones,  

 

期刊: Journal of Applied Physics  (AIP Available online 1965)
卷期: Volume 36, issue 3  

页码: 919-920

 

ISSN:0021-8979

 

年代: 1965

 

DOI:10.1063/1.1714262

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The55Mn NMR has been observed in the paramagnetic state of the antiferromagnet MnO. The separation between the absorption derivative extrema of the55Mn NMR is55(&dgr;H)≃340 Oe, in satisfactory agreement with the predictions of exchange narrowing of hyperfine broadened nuclear magnetic resonances in paramagnetic media. The55Mn NMR frequency shift55a=(&dgr;v/v) is found to be temperature dependent, varying from about −11.75% to −9.3% in the range 130° to 350°K. From the observed linear dependence of55aon the magnetic susceptibility, the hyperfine coupling constant is determined to be55A=−(81.5±1.6)×10−4cm−1. Combining the17O NMR data of O'Reilly and Tsang with the55Mn NMR data yields a value for the17O transferred hyperfine coupling constant of17A=(2.46±0.04)×10−4cm−1.

 

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