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An Attempt to Measure the First Normal‐Stress DifferenceN1in Shear Flow for a Polyisobutylene/Decalin Solution “D2b” at Shear Rates up to106 s−1

 

作者: A. S. Lodge,  

 

期刊: Journal of Rheology  (AIP Available online 1989)
卷期: Volume 33, issue 6  

页码: 821-841

 

ISSN:0148-6055

 

年代: 1989

 

DOI:10.1122/1.550066

 

出版商: The Society of Rheology

 

数据来源: AIP

 

摘要:

For a polyisobutylene/decalin solution “D2b,” agreement over a range of values of shear rate γ̇ up to29,000 s−1(where the stress ratioN1/σ=5;σ=shear stress) is found between values ofN1measured near 20°C using a Torsional Balance Rheometer (“TBR”) and a “Stressmeter” (“SM”, a slit‐die rheometer using transverse slots to measure hole pressures); viscosity values also agree. Time‐temperature superposition behavior exhibited by SM data taken in a temperature range 22–99°C suggest that the range of validity of the SM method for determiningN1approximately extends up toγ̇=1.3×106 s−1;here,N1/σ=10and, in the SM die, the Reynolds numberRe=100.This γ̇ value is four times higher than the greatest γ̇ value used in previous similar tests of the SM method made with a similar but more concentrated solution “D2”.

 

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