Competition between the Two Reduction Reactions of the γ(III) Phase in the Ni-Based Batteries
作者:
N. Sac-Epée,
M.R. Palacin,
A. Audemer,
B. Beaudoin,
A. Delahaye-vidal,
T. Jamin,
Y. Chabre,
J-M. Tarascon,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 311,
issue 1
页码: 115-121
ISSN:1058-725X
年代: 1998
DOI:10.1080/10587259808042375
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
We show that the γ(III)/β(II) phase transition is at the origin of the second plateau at 0.8V in the Ni-based batteries by means of transmission electron microscopy (TEM) and X-ray diffraction (XRD) studies and intermittent galvanostatic measurements (GITT). This study shows that the equilibrium voltage of this transition is 1.25V vs Cd-Cd(OH)2, thus implying an overvoltage of 400 mV. Direct evidence for a textural memory effect trough the γ(III)/β(II) phase transition is given by TEM studies. The reoxidation of the β(II) phase to γ(III) phase occurs without going trough the β(III) phase.
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