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Oxidative Polymerization of 2,6-Dimethylphenol by Copper(II)Chloride-Amine Complexes: Effect of Amines on Polymerization Activity

 

作者: SudhakarS. Mahajan,   BhaskarB. Idage,   BhimraoD. Sarawade,   NakayuN. Chavan,   Swaminathan Sivaram,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  （Taylor Available online 1991）
卷期: Volume 28, issue sup1  

页码: 7-13

 

ISSN:0022-233X

 

年代: 1991

 

DOI:10.1080/00222339108054377

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

2, 6-Dimethylphenol (2, 6-DMP) undergoes oxidative polymerization with CuCl2.2H2O-aliphatic amine complexes in a 70:30(v/v) o-dichlorobenzene-ethanol solvent. Unlike pyridine, polymerization occurs even in the absence of added base. Apart from basicity, factors such as steric effects and nature of ligand coordination to Cu(II) have profound effect on catalyst reactivity.

 

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