Use of cartridges for speciation of organotin compounds in environmental samples
作者:
J. L. Gomez‐Ariza,
R. Beltrán,
E. Morales,
I. Giraldez,
M. Ruiz‐Benitez,
期刊:
Applied Organometallic Chemistry
(WILEY Available online 1994)
卷期:
Volume 8,
issue 7‐8
页码: 553-561
ISSN:0268-2605
年代: 1994
DOI:10.1002/aoc.590080703
出版商: John Wiley&Sons, Ltd.
关键词: Tributyltin;dibutyltin;monobutyltin;triphenyltin;diphenyltin;monophenyltin;speciation;C18cartridges;C8cartridges;preconcentration;water
数据来源: WILEY
摘要:
AbstractThe performance of cartridges with different polar and non‐polar stationary phases (C18, C8, C2, phenyl) has been investigated for the quantitative separation of butyltin and phenyltin species (TBT, DBT, MBT, MPT, DPT, TPT), and conditions have been established to optimize the separation, using gas chromatography with a flame photometric detector, to characterize the different organotin species. Optimum separation and preconcentration of organotins is based on retention in a C18cartridge and elution with 2 cm3of 1% (v/v) HBr and 0.1% tropolone solution in methanol, being successfully applied to seawater. Finally, the possibilities of the cartridges for selective elution and their use in direct non‐chromatographic speciation are discus
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