Effect of Substituents on the Reaction of Aromatic Primary Amines with Fluorescamine
作者:
Hiroshi Nakamura,
Mayumi Takayama,
Zenzo Tamura,
Reiko Yoda,
Yuichi Yamamoto,
期刊:
Analytical Letters
(Taylor Available online 1982)
卷期:
Volume 15,
issue 7
页码: 657-680
ISSN:0003-2719
年代: 1982
DOI:10.1080/00032718208064408
出版商: Taylor & Francis Group
关键词: aromatic primary amines;substituent effect;fluorescamine;fluorescence reaction
数据来源: Taylor
摘要:
The effects of substituents on the reactivity of the monosubstituted anilines with fluorescamine (FLA) and the fluorescent properties of the reaction products, FI (Ph), were investigated. Generally, the substituent at o-position markedly inhibited the reactivity of the amino group (ortho-effect). While the electron-donating substituent seemed to be favorable for the formation of FI (Ph), the electron-attracting one seemed to lower reactivity of the amino group. However, the presence of the latter substituent led to the enhanced fluorescence of FI (Ph). The highly significant correlation was observed between the wavelengths (nm) of the emission maxima and the Hammett's substituent constants.
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