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Far infra-red spectra of molecular crystals

 

作者: A. Anderson,   H.A. Gebbie,   S.H. Walmsley,  

 

期刊: Molecular Physics  (Taylor Available online 1964)
卷期: Volume 7, issue 5  

页码: 401-409

 

ISSN:0026-8976

 

年代: 1964

 

DOI:10.1080/00268976300101171

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Absorption spectra of crystalline films of hydrogen and deuterium chloride and bromide at 77°khave been measured in the region 20–400 cm-1using a Michelson interferometer. The absorptions are assigned as lattice vibrations, and translational and torsional modes are distinguished. It is shown that the observed spectra are consistent with a crystalline structure of four molecules per unit cell in a planar array and approximate values of the principal intermolecular force constants are derived.

 

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