Far infra-red spectra of molecular crystals
作者:
A. Anderson,
H.A. Gebbie,
S.H. Walmsley,
期刊:
Molecular Physics
(Taylor Available online 1964)
卷期:
Volume 7,
issue 5
页码: 401-409
ISSN:0026-8976
年代: 1964
DOI:10.1080/00268976300101171
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Absorption spectra of crystalline films of hydrogen and deuterium chloride and bromide at 77°khave been measured in the region 20–400 cm-1using a Michelson interferometer. The absorptions are assigned as lattice vibrations, and translational and torsional modes are distinguished. It is shown that the observed spectra are consistent with a crystalline structure of four molecules per unit cell in a planar array and approximate values of the principal intermolecular force constants are derived.
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