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Density profiles of colloidal suspensions in equilibrium inside slit pores

 

作者: Guillermo Rodríguez,   Luis Vicente,  

 

期刊: Molecular Physics  (Taylor Available online 1996)
卷期: Volume 87, issue 1  

页码: 213-226

 

ISSN:0026-8976

 

年代: 1996

 

DOI:10.1080/00268979600100121

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The problem of sedimentation equilibrium is treated within the integral equation formalism of inhomogeneous fluids using the Ornstein-Zernike approach, and using the Percus-Yevick closure, to describe sterically stabilized and charged colloidal suspensions contained in pores of different size. The calculated density profiles exhibit pronounced oscillations near the bottom, showing layering, and, for large pores, a non-oscillatory tail, in agreement with Monte Carlo simulations. For small pores, the particle distribution includes the appearance of layers for small separations. In the case of bidispersions, the computation shows that for large pores there is non-monotonic behaviour by one of the components, owing to competition between excluded volume and gravity. A similar effect is shown in monocomponent systems if the particles interact via a Yukawa-type potential.

 

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