AbstractThe Calabrian–Peloritan Hercynian Range includes three weakly metamorphosed Palaeozoic sequences cropping out in north‐eastern Sila (Bocchigliero sequence), southern Sila, Serre and Aspromonte (Stilo sequence), and in the Peloritan Mountains (Peloritan sequence). The work reported here considers the Bocchigliero sequence and comprises part of a geological, petrological and geochemical research programme on the Palaeozoic evolution of the Calabrian–Peloritan Arc.The Bocchigliero sequence constitutes the lower tectonic unit of the Hercynian Caiabrian–Peloritan Range and is overthrusted by the metamorphic Mandatoriccio Unit. The Bocchigliero sequence is a terrigenous–carbonate–volcanic association, is affected byclow grade metamorphism, contains Cambro‐Ordovician fossils and extends in age from the Cambrian to the Devonian. The terrigenous material is represented by meta‐arenites and metapelites (Cambrian–Devonian); the volcanics include metatuffites (Cambrian and Ordovician), metabasalts (Cambro‐Ordovician), metaandesites and metarhyolites (Ordovician and Siluro‐Devonian); limestone beds are present in the Devonian. It is believed that the Palaeozoic Bocchigliero basin formed in the Cambrian on a continental crust in which the rocks constituting today's Mandatoriccio Unit were located at 3–8 km depth. The crustal thinning in the Cambro‐Ordovician led to fracturing and upwelling of alkaline within‐plate basaltic magmas, whereas in the Ordovician the thinning took place under conditions of higher plasticity. In this latter period an increase in temperature resulting from mantle upwelling produced crustal partial melts of andesite and rhyolite composition. In addition, this thermal uprise was responsible for regional metamorphism characterized by low pressures and by the absence of penetrative deformation. The effects of this metamorphism are well developed in the rocks of the Mandatoriccio Unit. In the Silurian and Devonian, progressive closing of the basin took place. The Palaeozoic sequence was then subjected to Variscan low pressure–low temperature metamo