Digital Simulation of a Rotating Disk Electrode with Optically Transparent Ring
作者:
R. Dörr,
E. W. Grabner,
期刊:
Berichte der Bunsengesellschaft für physikalische Chemie
(WILEY Available online 1978)
卷期:
Volume 82,
issue 2
页码: 164-168
ISSN:0005-9021
年代: 1978
DOI:10.1002/bbpc.197800005
出版商: Wiley‐VCH Verlag GmbH&Co. KGaA
关键词: Absorptionsspektren, sichtbar und ultraviolett;Apparate und Methoden;Elektrochemie;Reaktionskinetik
数据来源: WILEY
摘要:
AbstractThe numerical method of digital simulation has been applied to the rotating disk electrode with optically transparent ring which represents a new electrochemical system, developed recently by Debrodt and Heusler in order to detect directly intermediates of electrochemical reactions. The extinction has been calculated as function of the geometric arrangement of the electrode system and of the rate constant of a first‐order follow‐up reaction. By comparison of calculated working curves with absorption measurements kinetic parameters can be determi
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