Vibrational Spectroscopy of Lithium Manganese Spinel Oxides
作者:
C. Julien,
A. Rougier,
E. Haro-poniatowski,
G.A. Nazri,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 311,
issue 1
页码: 81-87
ISSN:1058-725X
年代: 1998
DOI:10.1080/10587259808042370
出版商: Taylor & Francis Group
关键词: lithium manganese oxide;vibrational spectroscopy;lithium batteries
数据来源: Taylor
摘要:
Lithiated spinel manganese oxides with various amounts of lithium have been prepared through solid-state reaction and electrochemical intercalation and deintercalation. Structures of the LixMn2O4samples with 0.3≤x≤1.2 are studied using X-ray diffraction and Rietveld refinement techniques. We report vibrational spectra of lithiated manganese oxides as a function of lithium concentration. The spectra of lithiated spinel manganese oxides have been analyzed on the basis of LiO4tetrahedra and MnO6octahedra when Li/Mn≤0.5, and LiO4, LiO6, and MnO6structural units when Li/Mn>0.5. Electrochemical performances of lithium manganese oxide are also studied.
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