AbstractAromatic polyamides were prepared from systematically halogenated terephthalic acids with hexamethylene diamine, piperazine, 4,4′‐diaminodiphenylether andp‐phenylene diamine by interfacial or low temperature solution polycondensation. The halogenated terephthalic acids used have mono‐, di‐, or tetra‐substituted fluorine, chlorine, or bromine atoms on the benzene ring. The nonhalogenated terephthalic acid was also used for the comparison. The effects of halogen substitution on the benzene ring on the synthesis and some properties of polymers were examined. Reduced specific viscosity decreased in the order F>Cl>Br by halogen substitution. The incorporation of halogen substituents on the ring led to a decrease of crystallinity and fluoro‐substituents hindered the crystallization more strongly. The melting point (Tm) decreased in the order F>Cl>Br by mono‐substitution, and Br>Cl>F by di‐and tetra‐substitution. The change ofTmcaused by the difference of the number of halogen substituents differed depending on the rigidity of polymer chains. The flame‐retardancy estimated by thermogravimetry, self‐ignition, and flash‐ignition test increased with increasing halogen content of the polymers. Solubility increased remarkably by halogen substitution. The peak temperature of tan δ decreased by halogen substitution. Some discussion was made on these effec