Solvent‐polymer interactions in the plasticisation of poly(ethylene terephthalate)
作者:
Wilfred Ingamells,
Nantaya Yanumet,
期刊:
British Polymer Journal
(WILEY Available online 1980)
卷期:
Volume 12,
issue 1
页码: 12-18
ISSN:0007-1641
年代: 1980
DOI:10.1002/pi.4980120104
出版商: John Wiley&Sons, Ltd
数据来源: WILEY
摘要:
AbstractThe effect of a range of chemically dissimilar solvents on the Tg of PET is dependent upon dispersion forces. A correlation is presented between the dispersion solubility parameters (δd) of the solvents and the reduction of theTgwhich they cause. Two experimentally determed values for the (δd) of PET are presented as evidence to support the claim that aromatic and cyclic solvents solvate the aromatic part of the repeat unit and aliphatic solvents solvate the aliphatic par
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